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The Relative Importance of the Various Greenhouse Gases

The question of the relative importance of the various greenhouse gases is not being answered in an intellectually satisfactory manner. A search of the internet yield a multitude of different figures for the share of the greenhouse effect that is attributable to, for example, water vapor and CO2. More perplexing is the fact that the figures are not given as single values but instead a wide range of values. One source says the share of long wave absorption by atmospheric CO2 is between 9 and 26 percent whereas the share for H2 in the form of water vapor or fog is between 66 and 85 percent. Another source gives the share for water vapor as 95 percent and that for CO2 as 3.6 percent. This is not a satisfactory situation.

Given that the different greenhouse gases have different effectivenesses in absorbing long wave radiation the distribution of greenhouse gases by mass or volume is irrelevant. A molecule of methane (CH4) is 28 times as effective in absorption of radiation than a modecule of CO2. A molecule of nitrous oxide (NO) is about 210 times as effective as a molecule of CO2. The first thing that is needed is then a tabulation of the relative effectiveness of the various greenhouse gases as absorbers of long wave radiation.

GasRelative
Effectiveness
(CO2=1.00)
Concentration
(ppm)
Weighted
Concentration


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